Adamantane-1-ammonium benzoate

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Adamantane-1-ammonium benzoate

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Adamantane-1-ammonium acetate

In the title compound, C(10)H(18)N(+)·C(2)H(3)O(2) (-), the ammonium H atoms of the cation are linked to three acetate anions via N-H⋯O hydrogen bonds, forming a chain structure extending along the b axis.

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Ammonium 2-(3,4-di­methyl­benzo­yl)benzoate dihydrate

In the anion of the title compound, NH4 (+)·C16H13O3 (-)·2H2O, the benzene rings are twisted with respect to each other by 73.56 (10)°. In the crystal, extensive N-H⋯O and O-H⋯O hydrogen bonds link the cations, anions and lattice water mol-ecules into a three dimensional supra-molecular structure.

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1-(2-Phenyl­eth­yl)adamantane

In the title compound, C(18)H(24), the adamantane cage consists of three fused cyclo-hexane rings in almost ideal chair conformations, with C-C-C angles in the range 108.0 (14)-111.1 (15)°. The phenyl and 1-adamantyl substituents adopt anti orientations with a C-C-C-C torsion angle of 177.10 (16)°. In the crystal packing, the mol-ecules are linked by weak C-H⋯π inter-actions into chains along t...

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The title compound, C(11)H(17)NS, is an important inter-mediate for the synthesis of biologically active adamantlythia-zolo-oxadiazo-les. The adamantyl residue is disordered about a twofold rotation axis over two sites with site-occupation factors of 0.817 (3) and 0.183 (3). The crystal structure is stabilized by inter-molecular N-H⋯S hydrogen-bonding inter-actions.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2009

ISSN: 1600-5368

DOI: 10.1107/s1600536809036903